The research activity of the Kortz group is in the field of synthetic inorganic and organometallic chemistry. We are particularly interested in the preparation and structural characterization of discrete polynuclear metal-oxo complexes called polyoxometalates (POMs). POMs have a tremendous structural variety and interesting properties in different fields including catalysis, energy, environment, medicine and materials science. The multitude of potential applications has led to significant interest in POMs worldwide. The first POM was prepared almost two centuries ago by Berzelius (1826), but it could be structurally characterized only 100 years later by Keggin (1933). Especially the availability of single-crystal X-ray diffraction has led to the discovery of a large number of novel POMs with different shape, size, and composition.
The research activities of the Kortz group at Jacobs University Bremen are mainly focused on (a) transition metal-substituted POMs, (b) hybrid organic-inorganic POMs, and (c) noble metal-based POMs. POMs are synthesized and structurally characterized at Jacobs University Bremen using a multitude of state-of-the art solution and solid-state analytical techniques (e.g. NMR, XRD, IR, UV-vis, AA, TGA-DSC). The catalytic, magnetic, biomedical, and electrochemical properties of the novel compounds are also investigated, at times involving expert colleagues from around the world. The Kortz group also has several industrially sponsored research projects in the areas of catalysis, energy, and environmental applications.
In 2008 the Kortz group discovered polyoxopalladates(II), a class of POMs based exclusively on square-planar coordinated Pd2+ addenda (as opposed to classical POMs, which are based on early d-block metal ions in high oxidations states). In 2010 the Kortz group also discovered polyoxoaurates(III). In 2005 the Kortz group discovered Cu20P8W48, a pioneering result demonstrating chemical reactivity of the large, wheel-shaped P8W48.
Selected Publications
- Structural overview and evolution paths of lacunary polyoxometalates
Liu, L.-L.; Wang, L.; Xiao, X.-Y.; Yang, P.; Zhao, J.; Kortz, U. Coord. Chem. Rev. 2024, 506, 215687. [Read Online] - Synthesis, structural elucidation and anticancer activity of diorganotin (IV) complexes derived from isonicotinoyl hydrazones
Ahsen, S.; Tanveer, I.; Uddin, N.; Yasmeen, T.; Abbas, S.; Naz, S.; Haider, A.; Bhattacharya, S.; Kortz, U.; Rashid, F. Inorg. Chim. Acta. 2024, 121965. [Read Online] -
Last piece of the puzzle: lead-assisted assembly of an arsenopalladate nanostar as antitumor metallodrug
Zhao, Y.; Li, C.-L.; Chen, C.-Q.; Du, J.; Kortz, U.; Gong, T.; Yang, P. Inorg. Chem. Front. 2024 [Read Online] - Peroxo‐Zr/Hf‐Containing Wells‐Dawson Polyoxometalates for H2O2‐based Homogeneous, Heterogeneous, and Biphasic Oxidation Catalysis
Sundar, A.; Maksimchuk, N. V.; Ivanchikova, I. D.; Zalomaeva, O. V.; Bajuk‐Bogdanović, D.; Kholdeeva, O. A.; Ćirić‐Marjanović, G.; Bassil, B. S.; Kortz, U. Chemistry Europe 2024, 2, e202300066. [Read Online] -
Discrete Platinum(II/IV)–Arsenito Clusters with Pt–As and Pt–O Bonding: [PtIV(As3O6)2]2–, [Pt4II(H2AsO3)6(HAsO3)2]2–, and [Pt2IIAs6W4O28]10–
Zhang, J.; Bhattacharya, S.; Nisar, T.; Wagner, V.; Kortz, U. Inorg. Chem. 2023, 62, 19603-19611. [Read Online] - Gallium(III)- and Thallium(III)-Encapsulated Polyoxopalladates: Synthesis, Structure, Multinuclear NMR and Biological Activity Studies
Ma, T.; Ma. X.; Lin, Z.; Zhang, J.; Yang, P.; Csupász, T.; Tóth, I.; Misirlic-Dencic, S.; Isakovic, M. A.; Lembo, D.; Donalisio, M.; Kortz, U. Inorg. Chem. 2023, 62, 33, 13195-13204. [Read Online] - PtIV-Containing Hexaplatinate(II) [PtIVPtII6O6(AsO2(CH3)2)6]2- and Hexapalladate(II) [PtIVPdII6O6(AsO2(CH3)2)6]2-
Zhang, J.; Bhattacharya, S.; Khsara, B. E.; Nisar, T.; Müller, A. B.; Besora, M.; Poblet, J. M.; Wagner, V.; Kuhnert, N.; Kortz, U. Inorg. Chem. 2023, 62, 33, 13184-13194 [Read Online] - Mixed Noble Metal-Oxo Clusters: Platinum(IV)-Gold(III) Oxoanion [PtIV2AuIII3O6((CH3)2AsO2)6]
Zhang, J.; Bhattacharya, S.; Müller, A. B.; Kiss, L.; Silvestru, C.; Kuhnert, N.; Kortz, U. Chem. Commun. 2023, 59, 5918-5921. [Read Online] - Polyoxidovanadates [MoVIVV9O28]5- and [H2PtIVVV9O28]5- interact with CHO cell plasma membrane lipids causing aggregation and activation of a G protein-coupled receptor
Kostenkova, K.; Althumairy, D.; Rajan, A.; Kortz, U.; Barisas. B. G.; Roess, D. A.; Crans. D. C. Front. Chem. Biol. 2023. [Read Online] - Tetra-MnIII-containing 30-Tungsto-4-phosphate [MnIII4(H2O)2(P2W15O56)2]12-: Entrapped PEDOT films, surface analysis and electrochemical study
Ali, B.; Sakthinathan, I.; Barreca, D.; Maccato, C.; Goura, J.; Kortz, U.; McCormac, T. Thin Solid Films. 2023, 76, 139610. [Read Online] - Electrocatalytic Oxygen Reduction Reaction on 48‑Tungsto‑8‑Phosphate Wheel Anchored on Carbon Nanomaterials
Novais. C. H.; Jarrais, B.; Haider, A.; Kortz, U.; Ruiz. G. A.; Ramos. R. I.; Freire. C.; Fernandes. M. D. Electrocatalysis 2023, 14, 294–305. [Read Online] - Mixed-Valent Palladium(IV/II)-Oxoanion, [PdIVO6PdII6((CH3)2AsO2)6]2-
Ma, X.; Bhattacharya, S.; Nisar, T.; Müller, A. B.; Wagner, V.; Kuhnert, N.; Kortz, U. Chem. Commun. 2023, 59, 904-907. [Read Online] - Discrete Arsonate-Grafted Inverted-Keggin 12-Molybdate Ion [Mo12O32(OH)2(4-N3C2H2-C6H4AsO3)4]2- and Formation of Copper(II)-Mediated Metal-Organic Framework
Ma, X.; Bhattacharya, S.; Taffa, D. H.; Nisar, T.; Wark, M.; Wagner, V.; Kortz, U. Inorg. Chem. 2023, 62, 1813–1819. [Read Online] - Host–Guest Chemistry in Discrete Polyoxo-12-Palladate(II) Cubes [MO8Pd12L8]n– (M = ScIII, CoII, CuII, L = AsO43–; M = CdII, HgII; L = PhAsO32–): Structure, Magnetism, and Catalytic Hydrogenation
Yang, P.; Elcheikh Mahmoud, M.; Xiang, Y.; Lin, Z.; Ma, X.; Christian, J. H.; Bindra, J. K.; Kinyon, J. S.; Zhao, Y.; Chen, C.; Nisar, T.; Wagner, V.; Dalal, N. S.; Kortz, U. Inorg. Chem. 2022, 61, 18524–18535. [Read Online] - Discovery of Polythioplatinate(II) [Pt3S2(SO3)6]10- and Study of Its Solution and Catalytic Properties
Rajan, A.; Elcheikh Mahmoud, M.; Wang, F.; Bhattacharya, S.; Mougharbel, A. S.; Ma, X.; Müller, A. B.; Nisar, T.; Taffa, D. H.; Poblet, J. M.; Kuhnert, N.; Wagner, V.; Wark, M.; Kortz, U. Inorg. Chem. 2022, 61, 11529−11538. [Read Online] - Organically Functionalized Mixed-Valent Polyoxo-30-molybdate Wheel and a Neutral Tetramolybdenum(V) Oxo Cluster
Sundar, A.; Bhattacharya, S.; Oberstein, J.; Ma, X.; Bassil, B. S.; Nisar, T.; Taffa, D. H.; Wark, M.; Wagner, V.; Kortz, U. Inorg. Chem. 2022, 61, 11524−11528. [Read Online] - Discrete, Cationic Palladium(II)-Oxo Clusters via f-Metal Ion Incorporation and their Macrocyclic Host-Guest Interactions with Sulfonatocalixarenes
Bhattacharya, S.; Barba-Bon, A.; Zewdie, T. A.; Müller, A. B.; Nisar, T.; Chmielnicka, A.; Rutkowska, I. A.; Schürmann, C. J.; Wagner, V.; Kuhnert, N.; Kulesza, P. J.; Nau, W. M.; Kortz, U. Angew. Chem. Int. Ed. 2022, 61, e202203114. [Read Online] - Organorhodium(III)- and Iridium(III)-Substituted 20-Tungstobismuthates(III) and -Antimonates(III), [(MCp*)2X2W20O70]10- (M = RhIII, IrIII; X = BiIII, SbIII)
Mougharbel, A. S.; Ahmedi, S.; Bhattacharya, S.; Rajan, A.; Kortz, U. ACS Omega 2021, 6, 34494−34500. [Read Online] - Metallodrug Profiling against SARS-CoV-2 Target Proteins Identifies Highly Potent Inhibitors of the S/ACE2 interaction and the Papain-like Protease PLpro
Gil-Moles, M.; Türck, S.; Basu, U.; Pettenuzzo, A.; Bhattacharya, S.; Rajan, A.; Ma, X.; Büssing, R.; Wölker, J.; Burmeister, H.; Hoffmeister, H.; Schneeberg, P.; Prause, A.; Lippmann, P.; Kusi-Nimarko, J.; Hassell-Hart, S.; McGown, A.; Guest, D.; Lin, Y.; Notaro, A.; Vinck, R.; Karges, J.; Cariou, K .; Peng, K.; Qin, X.; Wang, X.; Skiba, J.; Szczupak, L.; Kowalski, K.; Schatzschneider, U.; Hemmert, C.; Gornitzka, H.; Milaeva, E. R.; Nazarov, A. A.; Gasser, G.; Spencer, J.; Ronconi, L.; Kortz, U.; Cinatl, J.; Bojkova, D.; Ott, I. Chem. Eur. J. 2021, 27, 17928–17940. [Read Online] -
Discovery of a Neutral 40-PdII-Oxo Molecular Disk, [Pd40O24(OH)16{(CH3)2AsO2}16]: Synthesis, Structural Characterization and Catalytic Studies
Bhattacharya, S.; Ma, X.; Mougharbel, A. S.; Haouas, M.; Su, P.; Espenship, M. F.; Taffa, D. H.; Jaensch, H.; Bons, A. J.; Stuerzer, T.; Wark, M.; Laskin, J.; Cadot, E.; Kortz, U. Inorg. Chem. 2021, 60, 17339-17347. [Read Online] - Selected polyoxopalladates as promising and selective antitumor drug candidates
Isakovic, A. M.; Čolović, M. B.; Ma, T.; Ma, X.; Jeremic, M.; Gerić, M.; Gajski, G.; Misirlic-Dencic, S.; Kortz, U.; Krstic, D. J. Biol. Inorg. Chem. 2021, 26, 957–971. [Read Online] - NiII36-Containing 54-Tungsto-6-Silicate: Synthesis, Structure, Magnetic and Electrochemical Studies
Goura, J.; Bassil, B. S.; Ma, X.; Rajan, A.; Moreno-Pineda, E.; Schnack, J.; Ibrahim, M.; Powell, A. K.; Ruben, M.; Wang, J.; Ruhlmann, L.; Kortz, U. Chem. Eur. J. 2021, 27, 15081–15085. [Read Online] - Arsenic(III)-Capped 12-Tungsto-2-Arsenates(III) [M2(AsIIIW6O25)2(AsIIIOH)x]n- (M = CrIII, FeIII, ScIII, InIII, TiIV, MnII) and Their Magnetic Properties
Liu, W.; Kinyon, J. S.; Bassil, B. S.; Lin, Z.; Bindra, J. K.; Dalal, N. S.; Kortz, U. Inorg. Chem. 2021, 60, 8267–8275. [Read Online] - Arylarsonate- and Phosphonate-Capped Polyoxomolybdates, [(RC6H4As)2Mo6O24]n– and [(R’C6H4P)2Mo5O21]n–
Manna, P.; Bhattacharya, S.; Kortz, U. Inorg. Chem. 2021, 60, 7161–7167. [Read Online] - Towards size-controlled deposition of Pd nanoparticles from polyoxometalate precursors: an Electrochemical Scanning Tunneling Microscopy study
Bock, N.; Clercq, A. D.; Seidl, L.; Kratky, T.; Ma, T.; Günther, S.; Kortz, U.; Heiz, U.; Esch, F. ChemElectroChem. 2021, 8, 1280-1288. [Read Online] - Quo vadis, Polyoxometalate Chemistry?
Yang, P.; Kortz, U. In Comprehensive Coordination Chemistry III; Constable, E. C., Parkin, G., Que Jr, L., Eds., Vol. 7, Elsevier, 2021; pp 4–28. [Read Oline]
- PtIV– or MoVI-substituted decavanadates inhibit the growth of Mycobacterium smegmatis
Kostenkova, K.; Arhouma, Z.; Postal, K.; Rajan, A.; Kortz, U.; Nunes, G. G.; Crick, D. C.; Crans, D. C. J. Inorg. Biochem. 2021, 217, 111356. [Read Online]
- Synthesis, Structure, Electrochemistry and Magnetism of Cobalt-, Nickel- and Zinc-Containing [M4(OH)3(H2O)2(α-SiW10O36.5)2]13- (M = Co2+, Ni2+, Zn2+)
Haider, A.;Bassil, B. S.; Lin, Z.; Ma, X.; Haferl, P. J.; Bindra, J. K.; Kinyon, J.; Zhang, G.; Keita, B.; Dalal, N. S.; Kortz, U. Dalton Trans. 2021, 50, 3923-3930. [Read Online] - Discovery and Supramolecular Interactions of Neutral Palladium-Oxo Clusters Pd16 and Pd24
Bhattacharya, S.; Basu, U.; Haouas, M.; Su, P.; Espenship, M. F.; Wang, F.; Solé-Daura, A.; Taffa, D. H.; Wark, M.; Poblet, J. M.; Laskin, J.; Cadot, E.; Kortz, U. Angew. Chem. Int. Ed. 2021, 60, 3632–3639. [Read Online, Open Access] - Peroxo-Uranyl-Containing W48 Wheel: Synthesis, Structure and Detailed Infrared and Raman Spectroscopy Study
Goura, J.; Sundar, A.; Bassil, B. S.; Ćirić-Marjanović, G.; Bajuk-Bogdanović, D.; Kortz, U. Inorg. Chem. 2020, 59, 16789–16794. [Read Online] - Shape and Size Tuning of BiIII-Centered Polyoxopalladates: High Resolution 209Bi NMR and 205/206Bi Radiolabelling for Potential Pharmaceutical Applications
Manna, P.; Szücs, D.; Csupász, T.; Fekete, A.; Szikra, D.; Lin, Z.; Gáspár, A.; Bhattacharya, S.; Zulaica, A.; Tóth, I.; Kortz, U. Inorg. Chem. 2020, 59, 16769–16782. [Read Online] (Featured Article) - Growth of ultra-thin large sized 2D flakes at air-liquid interface to obtain 2D-WS2 monolayers
Nisar, T.; Balster, T.; Haider, A.; Kortz, U.; Wagner, V. J. Phys. D: Appl. Phys. 2020, 54, 065301. [Read Online]
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In Operando X‑ray Studies of High-Performance Lithium-Ion Storage in Keplerate-Type Polyoxometalate AnodesLin, C.-C.; Hsu, C.-T.; Liu, W.; Huang, S.-C.; Lin, M.-H.; Kortz, U.; Mougharbel, A. S.; Chen, T.-Y.; Hu, C.-W.; Lee, J.-F.; Wang, C.-C.; Liao, Y.-F.; Li, L.-J.; Li, L.; Peng, S.; Stimming, U.; Chen, H.-Y. ACS Appl. Mater. Interfaces, 2020, 12, 40296–40309. [Online]
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PolyoxometalatesBassil, B. S.; Kortz, U. in Rare Earth Chemistry, Ed. Pöttgen, R.; Jüstel, T.; Strassert, C. A., De Gruyter STEM, 2020. [Online]
- Palladium(II)-containing Tungstoarsenate(V), [PdII4(As2W15O56)2]16-, and its Catalytic Properties
Rajan, A.; Mougharbel, A. S.; Bhattacharya, S.; Nisar, T.; Wagner, V.; Kortz, U. Inorg. Chem. 2020, 59, 13042–13049. [Read Online] - Co-ion Effects in the Self-Assembly of Macroions: From Co-ions to Co-macroions and to the Unique Feature of Self-Recognition
Chen, J.; Qian, K.; Xiao, K.; Luo, J.; Li, H.; Ma, T.; Kortz, U.; Tsige, M.; Liu, T. Langmuir 2020, 36, 10519–10527. [Read Online] -
FeIII48-Containing 96-Tungsto-16-Phosphate: Synthesis, Structure, Magnetism and ElectrochemistryGoura, J.; Bassil, B. S.; Bindra, J. K.; Rutkowska, I. A.; Kulesza, P. J.; Dalal, N. S.; Kortz, U. Chem. Eur. J. 2020, 26, 15821–15824 [Read Online, Open Access]
- Tetra-MnIII-containing 30-Tungsto-4-phosphate, [MnIII4(H2O)2(P2W15O56)2]12-: Synthesis, Structure, XPS, Magnetism and Electrochemical Study
Goura, J.; Choudhari, M.; Nisar, T.; Balster, T.; Bindra, J. K.; Kinyon, J.; Ali, B.; McCormac, T.; Dalal, N. S.; Wagner, V.; Kortz, U. Inorg. Chem. 2020, 59, 13034-13041. [Read Online]. - Polyoxopalladate-loaded Metal-Organic Framework (POP@MOF): Synthesis and Heterogeneous Catalysis
Bhattacharya, S.; Ayass, W. W.; Taffa, D. H.; Nisar, T.; Balster, T.; Hartwig, A.; Wagner, V.; Wark, M.; Kortz, U. Inorg. Chem. 2020, 59, 10512−10521. [Read Online]. - Lanthanide-Containing 22-Tungsto-2-germanates [Ln(GeW11O39)2]13-: Synthesis, Structure, and Magnetic Properties
Mougharbel, A. S.; Bhattacharya, S.; Bassil, B. S.; Rubab, A.; van Leusen, J.; Kögerler, P.; Wojciechowski, J.; Kortz, U. Inorg. Chem. 2020, [Read Online] - Tetra-(p-tolyl)antimony(III)-containing Heteropolytungstates, [{(p-tolyl)SbIII}4(A-α-XW9O34)2]n- (X = P, As, Ge): Synthesis, Structure and Study of Antibacterial/Antitumor Activity
Ma, T.; Yang, P.; Dammann, I.; Lin, Z.; Mougharbel, A. S.; Li, M.-X.; Adăscăliţei, F.; Mitea, R.; Silvestru, C.; Thorstenson, C.; Ullrich, M. S.; Cseh, K.; Jakupec, M. A.; Keppler, B. K.; Donalisio, M.; Cavalli, R.; Lembo, D.; Kortz, U. Inorg. Chem. 2020, [Read Online] - 9-Cobalt(II)-Containing 27-Tungsto-3-Germanate(IV): Synthesis, Structure, Computational Modeling and Heterogeneous Water Oxidation Catalysis
Haider, A.; Bassil, B. S.; Soriano-López, J.; Qasim, H. M.; de Pipaón, C. S.; Ibrahim, M.; Dutta, D.; Koo, Y.-S.; Carbó, J. J.; Poblet, J. M.; Galán-Mascarós, J. R.; Kortz, U. Inorg. Chem. 2019, 58, 11308-11316. [Read Online] - Peroxo-Cerium(IV)-Containing Polyoxometalates: [CeIV6(O2)9(GeW10O37)3]24-, a Recyclable Homogeneous Oxidation Catalyst
Qasim, H. M.; Ayass, W. W.; Donfack, P.; Mougharbel, A. S.; Bhattacharya, S.; Nisar, T.; Balster, T.; Solé-Daura, A.; Römer, I.; Goura, J.; Materny, A.; Wagner, V.; Poblet, J. M.; Bassil, B. S.; Kortz, U. Inorg. Chem. 2019, 58, 11300-11307. [Read Online] - Fast Microwave-Assisted Synthesis of Wells-Dawson-Type 18-Tungsto-2-Phosphate [P2W18O62]6-
Pandya, V. M.; Haider, A.; Qasim, H. M.; Mougharbel, A. S.; Kortz, U.; Joshi, S. A. Inorganics 2019, 7, 23-28. [Read Online] - Syntheses, and Crystal Structures of YIII Containing Di-metal Substituted 1,5 Isomer of Heterometallic Tungstophosphate Nanoclusters: [Y{PM2W10O38(H2O)2}2]11- (M = CoII and ZnII)
Das, V.; Gupta, R.; Iseki, N.; Sadakane, M.; Mougharbel, A. S.; Kortz, U.; Hussain, F. ChemistrySelect 2019, 4, 2538-2544. [Read Online] - Multi-Electron Redox Chemistry of Wells-Dawson Polyoxometalate Films onto Metallic and Dielectric Substrates
Douvas, A. M.; Tsikrizis, D.; Tselios, C.; Kennou, S.; Haider, A.; Mougharbel, A. S.; Kortz, U.; Palilis, L. C.; Hiskia, A.; Coutsolelos, A. G.; Vasilopoulou, M.; Argitis, P. Phys. Chem. Chem. Phys. 2019, 21, 427-437. [Read Online] - Uniform Trend in Layer-by-Layer Deposition of Heteropolytungstates
Ball, V.; Mougharbel, A. S.; Kortz, U. J. Colloid Interface Sci. 2019, 533, 771–778. [Read Online] - [(SeO)4P8W48O184]32–: a Tetraselenite-Embedded Derivative of the Cyclic 48-Tungsto-8-Phosphate
Wang, K.-Y.; Zhang, S.; Ding, D.; Ma, T.; Kortz, U.; Wang, C. Eur. J. Inorg. Chem. 2019, 512–516. [Read Online] - Selective Rb+ vs K+ Guest Incorporation in Wheel-Shaped 27-Tungsto-3-Arsenate(III) Host, [M⊂{(β-AsIIIW8O30)(WO(H2O))}3]14- (M = K, Rb)
Kandasamy, B.; Sudmeier, T.; Ayass, W. W.; Lin, Z.; Feng, Q.; Bassil, B. S.; Kortz, U. Eur. J. Inorg. Chem. 2019, 502-505.[Read Online] - Bismuth(III)-Containing Heteropolytungstates, [Bi(XW11O39)2]n- (X = Si, Ge, n = 13; X = P, n = 11) and [Bi(P2W17O61)2]17-
Ncube, N.; Bhattacharya, S.; Thiam, D.; Goura, J.; Mougharbel, A. S.; Kortz, U. Eur. J. Inorg. Chem. 2019, 363–366. [Read Online] - Celebrating Polyoxometalate Chemistry
Pope. M. T.; Sadakane. M.; Kortz. Ulrich. Eur. J. Inorg. Chem. 2019, 340–342. [Read Online] - Special issue on Polyoxometalates
Galán-Mascarós, J. R.; Kortz, U. Acta Crystallogr. 2018, C74, 1180-1181. [Read Online] - The Mixed-Valent 10-Manganese(III/IV)-Containing 36-Tungsto-4-Arsenate(V), [MnIII6MnIV4O4(OH)12(H2O)12(A-β-AsW9O34)4]22-
Al-Oweini, R.; Bassil, B. S.; Itani, M.;Emiroğlu, D. B.; Kortz, U. Acta Crystallogr. 2018, C74, 1390–1394. [Read Online] - 15-Copper(II)-Containing 36-Tungsto-4-silicates(IV) [Cu15O2(OH)10X(A-α-SiW9O34)4]25- (X = Cl, Br): Synthesis, Structure, Magnetic Properties, and Electrocatalytic CO2 Reduction
Bassil, B. S.; Haider, A.; Ibrahim, M.; Mougharbel, A. S.; Bhattacharya, S.; Christian, J. H.; Bindra, J. K.; Dalal, N. S.; Wang, M.; Zhang, G.; Keita, B.; Rutkowska, I. A.; Kulesza, P. J.; Kortz, U. Dalton Trans. 2018, 47, 12439–12448. [Read Online] - Preyssler-Pope-Jeannin Polyanions [NaP5W30O110]14- and [AgP5W30O110]14-: Microwave-Assisted Synthesis, Structure, and Biological Activity
Haider, A.; Zarschler, K.; Joshi, S. A.; Smith, R. M.; Lin, Z.; Mougharbel, A. S.; Herzog, U.; Müller, C. E.; Stephan, H.; Kortz, U. Z. Anorg. Allg. Chem. 2018, 644, 752–758. [Read Online] - Mechanism of Sodium Ion Storage in Na7[H2PV14O42] Anode for Sodium–Ion Batteries
Lin, C.-C.; Lin, W.-H.; Huang, S.-C.; Hu, C.-W.; Chen, T.-Y.; Hsu, C.-T.; Yang, H.; Haider, A.; Lin, Z.; Kortz, U.; Stimming, U.; Chen, H.-Y. Adv. Mater. Interf. 2018, 5, 1800491. [Read Online] - Dithallium(III)-Containing 30-Tungsto-4-phosphate, [Tl2Na2(H2O)2(P2W15O56)2]16-: Synthesis, Structural Characterization, and Biological Studies
Ayass, W. W.; Fodor, T.; Farkas, E.; Lin, Z.; Qasim, H. M.; Bhattacharya, S.; Mougharbel, A. S.; Abdallah, K.; Ullrich M. S.; Zaib, S.; Iqbal, J.; Harangi, S.; Szalontai, G.; Bányai, I.; Zékány, L.; Tóth, I.; Kortz, U. Inorg. Chem. 2018, (in press) - Remember the Keggin Ion?
Ayass, W. W.; Kortz, U. ChemViews Mag. 2018 [https://doi.org/10.1002/chemv.201800009] - Reinvestigation of Dilacunary 19-Tungsto-2-Arsenate(III) [AsIII2W19O67(H2O)]14- Including 183W NMR Solution Study
Wang, K.-Y.; Bassil, B. S.; Carey, A. M.; Mougharbel, A. S.; Kortz, U. Eur. J. Inorg. Chem. 2017, 4210–4213.[Read Online] - Incorporation of Transition Metal Ion Guests (Co2+, Ni2+, Cu2+, Zn2+) into the Ti2-containing 18-Tungsto-2-Arsenate(III) Monolacunary Host
Wang, K.-Y.; Bassil, B. S.; Xing, X.; Keita, B.; Bindra, J. K.; Diefenbach, K.; Dalal, N. S.; Kortz, U. Eur. J. Inorg. Chem. 2016, 5519–5529. [Read Online]
This paper has a video abstract [View video] - Chiral Dodecanuclear Palladium(II)-Thio Cluster: Synthesis, Structure, and Formation Mechanism Explored by ESI-MS and DFT Calculations
Lin, Z.; Fan, L.; Kondinski, A.; Vankova, N.; Heine, T.; Chen, B.; Haider, A.; Wang, B.; Kortz, U.; Hu, C. Inorg. Chem. 2016, 55, 7811−7813.[Read Online] - Platinum-Containing Polyoxometalates: syn- and anti-[PtII2(α-PW11O39)2]10– and Formation of the Metal-Metal bonded di-PtIII Derivatives
Lin, Z.; Izarova, N. V.; Kondinski, A.; Xing, X.; Haider, A.; Fan, L.; Vankova, N.; Heine, T.; Keita, B.; Cao, J.; Hu, C.; Kortz, U. Chem. Eur. J. 2016, 22, 5514-5519.[Read Online] - Mixed-Valent Mn16-Containing Heteropolyanions: Oxidation State Tuning and Resulting Physicochemical Properties
Haider, A.; Ibrahim, M.; Bassil, B. S.; Carey, A.M.; Nguyen Viet, A.; Xing, X.; Ayass, W. W.; Miñambres, J. F.; Liu, R.; Zhang, G.; Keita, B.; Mereacre, V.; Powell, A. K.; Balinski, K.; N’Diaye, A. T.; Kuepper, K.; Chen, H.-Y.; Stimming, U.; Kortz, U. Inorg. Chem. 2016, 55 , 2755-2764. [Read Online] - Characterization of PtIV-containing Polyoxometalates by High-Resolution Solid-State 195Pt and 51V NMR Spectroscopy
Dugar, S.; Izarova, N. V.; Mal, S. S.; Fu, R.; Joo, H.-C.; Lee, U.; Dalal, N. S.; Pope, M. T.; Jameson, G. B.; Kortz, U. New J. Chem. 2016, 40, 923-927. [Read Online] - Polyoxometalates
Pope, M. T.; Kortz, U. Encyclopedia of Inorganic and Bioinorganic Chemistry 2012. [Read Online] - Recent Advances in Lanthanide-Containing Polyoxotungstates
Bassil, B. S.; Kortz, U., Z. Anorg. Allg. Chem. 2010, 636, 2222-2231. [Read Online]